CITGO PETROLEUM CORP LEMONT REFINERY
                    CITGO HOLDING INC
                    Facility Summary
                        135TH ST & NEW AVE, LEMONT, IL, 60439 (WILL)
                                In 2022, this facility made toxic releases of:
                                                                            - Concern to the air
                                                                                                                                                                                                                                                                - Onsite air release of Clean Air Act chemicals
                                                                                                                                                    - Onsite release Persistent bioaccumulative toxic substance (PBTs)
                                                                                                                - Onsite release of known carcinogens
                                                                                                                                                                                    
                                    This facility reported the following greenhouse gas releases for 2022:
                                                                                            - 3,658.25 metric tons of Methane (CH4)
                                                                                            - 1,138.66 metric tons of Nitrous Oxide (N2O)
                                                                                            - 655,472.20 metric tons of Carbon Dioxide (CO2)
                                                                                                                        18-month enforcement and compliance history summary for this facility:
                                        
                                                                                                                                Facility: Violation Identified
                                                                
                                                                Clean Air Act: Violation w/in 1 Year
                                                                Clean Water Act: No Violation Identified
                                                                Resource Conservation and Recovery Act : No Violation Identified
                                                                                                                                    Total Penalties: $0
                                                                                                                                                                                                    Last Penalty: 01/11/2017
                                                                                                                        2022 Toxic Substance Releases
        
        | Substance | Total (lbs)  | 
                            Air (lbs)  | 
                            Water (lbs)  | 
                            Land (lbs)  | 
                            UnInj (lbs)  | 
                            Offsite (lbs)  | 
                        
|---|---|---|---|---|---|---|
| 
                            HYDROGEN SULFIDE
            
             CASRN: 6/4/83  | 
                40,044.00 | 40,044.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a developmental or reproductive toxin. 
    (Source: California Proposition 65)
 
    
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            BENZENE
            
             CASRN: 71-43-2  | 
                20,313.00 | 20,173.00 | 46.00 | 0.00 | 0.00 | 94.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: International Agency for Research on Cancer Monographs On the Evaluation of Carcinogenic Risks to Humans)
 
    
    
            
 This substance is a developmental or reproductive toxin. 
    (Source: California Proposition 65)
 
    
            
 This substance is a mutagen. 
    (Source: European Chemical Agency InfoCards)
 
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            AMMONIA
            
             CASRN: 7664-41-7  | 
                17,080.00 | 16,506.00 | 574.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            N-HEXANE
            
             CASRN: 110-54-3  | 
                15,890.00 | 15,844.00 | 46.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a developmental or reproductive toxin. 
    (Source: California Proposition 65)
 
    
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            TOLUENE
            
             CASRN: 108-88-3  | 
                13,841.00 | 13,730.00 | 46.00 | 0.00 | 0.00 | 65.00 | 
| 
             
 This substance is a developmental or reproductive toxin. 
    (Source: California Proposition 65)
 
    
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            SULFURIC ACID
            
             CASRN: 7664-93-9  | 
                13,607.00 | 13,607.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: U.S. Dept. of Health & Human Services 15th Report on Carcinogens)
 
    
    
    
    
    
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            NITRATE COMPOUNDS (WATER DISSOCIABLE)
            
             CASRN: N511  | 
                13,043.00 | 0.00 | 13,043.00 | 0.00 | 0.00 | 0.00 | 
| 
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            VANADIUM COMPOUNDS
            
             CASRN: N770  | 
                8,245.00 | 63.00 | 5,142.00 | 0.00 | 0.00 | 3,040.00 | 
| 
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            XYLENES
            
             CASRN: 1330-20-7  | 
                7,878.00 | 7,589.00 | 92.00 | 0.00 | 0.00 | 197.00 | 
| 
             
 This substance is a developmental or reproductive toxin. 
    (Source: Plastichem Project)
 
    
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            ETHYLBENZENE
            
             CASRN: 100-41-4  | 
                7,264.00 | 7,182.00 | 46.00 | 0.00 | 0.00 | 36.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens)
 
    
    
            
 This substance is a developmental or reproductive toxin. 
    (Source: Plastichem Project)
 
    
            
 This substance is a mutagen. 
    (Source: European Chemical Agency InfoCards)
 
    
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            ZINC COMPOUNDS
            
             CASRN: N982  | 
                7,138.00 | 523.00 | 0.00 | 0.00 | 0.00 | 6,615.00 | 
| 
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            ETHYLENE
            
             CASRN: 74-85-1  | 
                6,233.00 | 6,233.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
    
    
    
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            PROPYLENE
            
             CASRN: 115-07-1  | 
                2,852.00 | 2,852.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
    
    
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            CUMENE
            
             CASRN: 98-82-8  | 
                2,452.00 | 2,452.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens)
 
    
    
    
            
 This substance is a mutagen. 
    (Source: European Chemical Agency InfoCards)
 
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            POLYCYCLIC AROMATIC COMPOUNDS (TRI CATEGORY)
            
             CASRN: N590  | 
                2,142.00 | 2,127.00 | 15.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This is a persistent bioaccumulative toxic substance (PBTs). 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
    
            
 This substance is a carcinogen. 
    (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens)
 
    
    
    
    
    
    
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            CYCLOHEXANE
            
             CASRN: 110-82-7  | 
                1,665.00 | 1,570.00 | 92.00 | 0.00 | 0.00 | 3.00 | 
| 
             
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            LEAD COMPOUNDS
            
             CASRN: N420  | 
                1,492.00 | 17.00 | 0.00 | 0.00 | 0.00 | 1,475.00 | 
| 
             
 This is a persistent bioaccumulative toxic substance (PBTs). 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
    
            
 This substance is a carcinogen. 
    (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens)
 
    
    
    
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
    
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            CHROMIUM COMPOUNDS
            
             CASRN: N090  | 
                1,445.00 | 52.00 | 92.00 | 0.00 | 0.00 | 1,301.00 | 
| 
             
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            MERCURY COMPOUNDS
            
             CASRN: N495  | 
                1,111.00 | 91.00 | 195.00 | 0.00 | 0.00 | 825.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens)
 
    
    
    
    
    
    
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            MOLYBDENUM TRIOXIDE
            
             CASRN: 1313-27-5  | 
                920.00 | 0.00 | 920.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens)
 
    
    
    
    
    
    
    
    
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            NAPHTHALENE
            
             CASRN: 91-20-3  | 
                626.00 | 557.00 | 6.00 | 0.00 | 0.00 | 63.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens)
 
    
    
    
    
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            PHENOL
            
             CASRN: 108-95-2  | 
                407.00 | 75.00 | 239.00 | 0.00 | 0.00 | 93.00 | 
| 
             
 This substance is a developmental or reproductive toxin. 
    (Source: Plastichem Project)
 
    
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            1,2,4-TRIMETHYLBENZENE
            
             CASRN: 95-63-6  | 
                337.00 | 277.00 | 46.00 | 0.00 | 0.00 | 14.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: Plastichem Project)
 
    
    
    
    
    
    
    
    
             | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            CARBON DISULFIDE
            
             CASRN: 75-15-0  | 
                290.00 | 290.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a developmental or reproductive toxin. 
    (Source: California Proposition 65)
 
    
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            BIPHENYL
            
             CASRN: 92-52-4  | 
                251.00 | 251.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: Plastichem Project)
 
    
    
    
    
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            METHYL ALCOHOL
            
             CASRN: 67-56-1  | 
                236.00 | 236.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a developmental or reproductive toxin. 
    (Source: California Proposition 65)
 
    
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
            
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            CARBONYL SULFIDE
            
             CASRN: 463-58-1  | 
                199.00 | 199.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            COBALT COMPOUNDS
            
             CASRN: N096  | 
                154.00 | 9.00 | 0.00 | 0.00 | 0.00 | 145.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens)
 
    
    
    
    
    
    
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            ANTIMONY COMPOUNDS
            
             CASRN: N010  | 
                49.00 | 12.00 | 0.00 | 0.00 | 0.00 | 37.00 | 
| 
             
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            CHLORINE
            
             CASRN: 7782-50-5  | 
                48.00 | 48.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            MERCURY COMPOUNDS
            
             CASRN: N458  | 
                24.20 | 7.00 | 0.20 | 0.00 | 0.00 | 17.00 | 
| 
             
 This is a persistent bioaccumulative toxic substance (PBTs). 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
    
    
    
    
    
    
    
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            BENZO[G,H,I]PERYLENE
            
             CASRN: 191-24-2  | 
                24.00 | 0.00 | 2.00 | 0.00 | 0.00 | 22.00 | 
| 
             
 This is a persistent bioaccumulative toxic substance (PBTs). 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
    
    
    
    
    
    
    
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            HYDROFLUORIC ACID
            
             CASRN: 7664-39-3  | 
                19.00 | 19.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is an asthmagen. 
    (Source: Association of Occupational and Environmental Clinics (AOEC))
 
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite | 
| 
                            1,3-BUTADIENE
            
             CASRN: 106-99-0  | 
                2.00 | 2.00 | 0.00 | 0.00 | 0.00 | 0.00 | 
| 
             
 This substance is a carcinogen. 
    (Source: International Agency for Research on Cancer Monographs On the Evaluation of Carcinogenic Risks to Humans)
 
    
    
            
 This substance is a developmental or reproductive toxin. 
    (Source: California Proposition 65)
 
    
            
 This substance is a mutagen. 
    (Source: European Chemical Agency InfoCards)
 
    
            
 This substance is a neurotoxin. 
    (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity)
 
    
            
 This substance is an endocrine disruptor. 
    (Source: TEDX (The Endocrine Disruption eXchange))
 
    
    
    
            
 This substance is a clean air act chemical. 
    (Source: U.S. EPA Toxics Release Inventory (TRI))
 
         | 
    ||||||
| Substance | Total | Air | Water | Land | UnInj | Offsite |