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CALUMET SHREVEPORT REFINING LLC

CALUMET REFINING LLC

Facility Summary

3333 MIDWAY ST, SHREVEPORT, LA, 71109 (CADDO PARISH)

In 2022, this facility made toxic releases of:

- Concern to the air

- Onsite air release of Clean Air Act chemicals

- Onsite release Persistent bioaccumulative toxic substance (PBTs)

- Onsite release of known carcinogens

This facility reported the following greenhouse gas releases for 2022:

- 585.25 metric tons of Methane (CH4)

- 7.45 metric tons of Nitrous Oxide (N2O)

- 4,009.80 metric tons of Carbon Dioxide (CO2)

18-month enforcement and compliance history summary for this facility:

Facility: Significant Violation

Clean Air Act: Violation Addressed; EPA Has Lead Enforcement

Clean Water Act: Violation Identified

Resource Conservation and Recovery Act : No Violation Identified

Total Penalties: $138,078

Last Penalty: 08/17/2022

2022 Toxic Substance Releases

Substance	Total (lbs)	Air (lbs)	Water (lbs)	Land (lbs)	UnInj (lbs)	Offsite (lbs)
N-HEXANE CASRN: 110-54-3	48,453.83	48,451.60	0.00	2.23	0.00	0.00
This substance is a developmental or reproductive toxin. (Source: California Proposition 65) This substance is a neurotoxin. (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC)) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
NITRATE COMPOUNDS (WATER DISSOCIABLE) CASRN: N511	44,032.40	0.00	44,032.40	0.00	0.00	0.00


Substance	Total	Air	Water	Land	UnInj	Offsite
TOLUENE CASRN: 108-88-3	18,255.63	16,586.30	0.00	200.04	0.00	1,469.29
This substance is a developmental or reproductive toxin. (Source: California Proposition 65) This substance is a neurotoxin. (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC)) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
AMMONIA CASRN: 7664-41-7	11,688.50	8,326.20	3,362.30	0.00	0.00	0.00
This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC))

Substance	Total	Air	Water	Land	UnInj	Offsite
XYLENES CASRN: 1330-20-7	9,939.81	9,189.60	0.00	4.52	0.00	745.69
This substance is a developmental or reproductive toxin. (Source: Plastichem Project) This substance is a neurotoxin. (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC)) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
BENZENE CASRN: 71-43-2	8,502.32	8,165.50	0.00	1.82	0.00	335.00
This substance is a carcinogen. (Source: International Agency for Research on Cancer Monographs On the Evaluation of Carcinogenic Risks to Humans) This substance is a developmental or reproductive toxin. (Source: California Proposition 65) This substance is a mutagen. (Source: European Chemical Agency InfoCards) This substance is a neurotoxin. (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC)) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
1,2,4-TRIMETHYLBENZENE CASRN: 95-63-6	5,886.16	4,652.20	0.00	0.00	0.00	1,233.96
This substance is a carcinogen. (Source: Plastichem Project)

Substance	Total	Air	Water	Land	UnInj	Offsite
PROPYLENE CASRN: 115-07-1	2,416.50	2,416.50	0.00	0.00	0.00	0.00
This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange))

Substance	Total	Air	Water	Land	UnInj	Offsite
HYDROGEN SULFIDE CASRN: 6/4/83	1,318.46	802.20	0.00	1.51	0.00	514.75
This substance is a developmental or reproductive toxin. (Source: California Proposition 65) This substance is a neurotoxin. (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC))

Substance	Total	Air	Water	Land	UnInj	Offsite
ETHYLBENZENE CASRN: 100-41-4	1,313.52	1,306.70	0.00	3.29	0.00	3.53
This substance is a carcinogen. (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens) This substance is a developmental or reproductive toxin. (Source: Plastichem Project) This substance is a mutagen. (Source: European Chemical Agency InfoCards) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC)) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
CYCLOHEXANE CASRN: 110-82-7	1,233.16	734.20	0.00	2.06	0.00	496.90
This substance is a neurotoxin. (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC))

Substance	Total	Air	Water	Land	UnInj	Offsite
DIOLAMINE CASRN: 111-42-2	416.10	38.40	0.00	89.50	0.00	288.20
This substance is a carcinogen. (Source: California Proposition 65) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC)) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
CARBON DISULFIDE CASRN: 75-15-0	309.70	309.70	0.00	0.00	0.00	0.00
This substance is a developmental or reproductive toxin. (Source: California Proposition 65) This substance is a neurotoxin. (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC)) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
NAPHTHALENE CASRN: 91-20-3	225.95	218.10	0.00	3.62	0.00	4.23
This substance is a carcinogen. (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC)) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
TETRACHLOROETHYLENE CASRN: 127-18-4	64.69	54.00	0.00	0.00	0.00	10.69
This substance is a carcinogen. (Source: International Agency for Research on Cancer Monographs On the Evaluation of Carcinogenic Risks to Humans) This substance is a neurotoxin. (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC)) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
ETHYLENE GLYCOL CASRN: 107-21-1	38.16	19.10	0.00	19.06	0.00	0.00
This substance is a developmental or reproductive toxin. (Source: California Proposition 65) This substance is a mutagen. (Source: Plastichem Project) This substance is a neurotoxin. (Source: Grandjean P, Landrigan PJ. Neurobehavioural effects of developmental toxicity) This substance is an endocrine disruptor. (Source: TEDX (The Endocrine Disruption eXchange)) This substance is an asthmagen. (Source: Association of Occupational and Environmental Clinics (AOEC)) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
POLYCYCLIC AROMATIC COMPOUNDS (TRI CATEGORY) CASRN: N590	0.80	0.80	0.00	0.00	0.00	0.00
This is a persistent bioaccumulative toxic substance (PBTs). (Source: U.S. EPA Toxics Release Inventory (TRI)) This substance is a carcinogen. (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite
MOLYBDENUM TRIOXIDE CASRN: 1313-27-5	0.00	0.00	0.00	0.00	0.00	0.00
This substance is a carcinogen. (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens)

Substance	Total	Air	Water	Land	UnInj	Offsite
MERCURY COMPOUNDS CASRN: N495	0.00	0.00	0.00	0.00	0.00	0.00
This substance is a carcinogen. (Source: U.S. Environmental Protection Agency Toxics Release Inventory Basis of OSHA Carcinogens) This substance is a clean air act chemical. (Source: U.S. EPA Toxics Release Inventory (TRI))

Substance	Total	Air	Water	Land	UnInj	Offsite